To unlock Dark Globox, win the first Obstacle Course Cup.

To unlock the Henchman 1000, win the first Total Fight circuit.

To unlock Mrs. Razorbeard, beat the first Freeze Combat circuit.

To unlock Tily, beat the first Time Attack circuit.

Beat All 4 Modes on the Pro Cup setting to unlock Master Mode. In Master mode you play against Dark Rayman in harder versions of the 4 modes.

Race: Beat Dark Rayman in 1 lap Races (All 12)
Time Attack: Get to the checkpoint 3 secs before Dark Rayman to Eliminate him. (All 12 races)
All out fight: Beat Dark Rayman in a 1 min battle at all levels.
Freeze Tag: Get more lums than Rayman in 1 min. At all levels, also the game is Cel Shaded in this mode.